TOPIC 6.2: STRATOSPHERIC OZONE
The ozone layer is the part of the Earth's atmosphere which contains relatively high concentrations of ozone (O3). "Relatively high" means a few parts per million - much higher than the concentrations in the lower atmosphere but still small compared to the main components of the atmosphere. Although the concentration of ozone in the ozone layer is very small, it is vitally important to life because it absorbs biologically harmful ultraviolet (UV) radiation from the Sun. The "thickness" of the ozone layer - that is, the total amount of ozone in a column overhead - varies by a large factor worldwide, being in general smaller near the equator and larger as one moves towards the poles. It also varies with season, being in general thicker during the spring and thinner during the autumn.
In this unit unit we will look at how human activities have resulted in the depletion of the ozone layer and the roles of government and non-government agencies in controlling the restricting ozone depleting substances.
This unit is a minimum of 2.5 hours.
Stratospheric ozone is a key component of the atmospheric system because it protects living systems from the negative effects of ultraviolet radiation from the Sun.
Human activities have disturbed the dynamic equilibrium of stratospheric ozone formation.
Pollution management strategies are being employed to conserve stratospheric ozone.
To what extent have the solutions emerging form this topic been directed at preventing environmental impacts, limiting the extent of the environmental impacts or restoring systems in which environmental impacts have already occurred?
How are the issues addressed in this topic of relevance to sustainability or sustainable development?
In what ways might the solutions explored in this topic after your predictions for the state of human societies and the biosphere some decades from now?
Why has the Montreal Protocol been so successful? Will it continue to be successful?
Outline the links between stratospheric ozone and sustainability/sustainable development.
What are the greatest threats to stratospheric ozone likely to be, and from where, in the decades to come?
Knowledge and Understanding
6.2.U1 Some ultraviolet radiation from the Sun is absorbed by stratospheric ozone causing the ozone molecule to break apart. Under normal conditions the ozone molecule will reform. This ozone destruction and reformation is an example of a dynamic equilibrium.
Ozone plays a key role in the temperature structure of the Earth's atmosphere. Without the filtering action of the ozone layer, more of the Sun's UV-B radiation would penetrate the atmosphere and would reach the Earth's surface. Ultraviolet radiation is absorbed during the formation and destruction of ozone from oxygen. You do not need to memorise chemical equations is not required.
6.2.U2 Ozone depleting substances (including halogenated organic gases such as chlorofluorocarbons—CFCs) are used in aerosols, gas-blown plastics, pesticides, flame retardants and refrigerants. Halogen atoms (such as chlorine) from these pollutants increase destruction of ozone in a repetitive cycle, allowing more ultraviolet radiation to reach the Earth.
[The use of chemical symbols, formulae or equations for the destruction of ozone is not required.]
Halogenated organic gases are very stable under normal conditions but can liberate halogen atoms when exposed to ultraviolet radiation in the stratosphere. These atoms react with monatomic oxygen and slow the rate of ozone
re‑formation. Pollutants enhance the destruction of ozone, thereby disturbing the equilibrium of the ozone production system
How ozone is depleted by CFC’s:
UV radiation breaks off a chlorine atom from a CFC molecule.
The chlorine atom attacks an ozone molecule (O3), breaking it apart and destroying the ozone.
The result is an ordinary oxygen molecule (O2) and a chlorine monoxide molecule (ClO).
The chlorine monoxide molecule (ClO) is attacked by a free oxygen atom releasing the chlorine atom and forming an ordinary oxygen molecule (O2).
The chlorine atom is now free to attack and destroy another ozone molecule (O3). One chlorine atom can repeat this destructive cycle thousands of times.
6.2 U3 Ultraviolet radiation reaching the surface of the Earth damages human living tissues, increasing the incidence of cataracts, mutation during cell division, skin cancer and other subsequent effects on health.
image from www.eoearth.org
Effects of UV on living organisms
Increase in mutation rates in DNA causing cancer
Can cause eye cataracts
Can damage the ability to carry out photosynthesis in plants and phytoplankton
Reduces primary production and therefore total productivity
Damage to immune system
6.2.U4 The effects of increased ultraviolet radiation on biological productivity include damage to photosynthetic organisms, especially phytoplankton, which form the basis of aquatic food webs.
UV-B radiation has been shown to be harmful to living organisms, damaging DNA, proteins, lipids and membranes. Plants, which use sunlight for photosynthesis and are unable to avoid exposure to enhanced levels of UV-B radiation, are at risk. UV-B impairs photosynthesis in many species. Overexposure to UV-B reduces size, productivity, and quality in many of the crop plant species that have been studied (among them, many varieties of rice, soybeans, winter wheat, cotton, and corn). Similarly, overexposure to UV-B impairs the productivity of phytoplankton in aquatic ecosystems. UV-B increases plant's’ susceptibility to disease. The effects also include mutation and subsequent effects on health and damage to photosynthetic organisms, especially phytoplankton and their consumers such as zooplankton.
6.2.U5 Pollution management may be achieved by reducing the manufacture and release of ozone-depleting substances. Methods for this reduction include:
developing alternatives to gas-blown plastics, halogenated pesticides, propellants and aerosols
developing non-propellant alternatives.
Replace the old fridge with the existing "greenfreeze" technology which does not deplete the ozone
Recycle old CFC coolants from old fridges and air conditioners
Protection from excess UV e.g. sunglass and sun block
Alternatives to gas-blown plastics
Alternatives to methyl bromide (bromomethane).
6.2.U6 UNEP has had a key role in providing information, and creating and evaluating international agreements, for the protection of stratospheric ozone.
United Nations Environment Programme (UNEP) in forging international agreements
ITIHC (International Trade in Harmful Chemicals)
contamination of international waterways
provide information to countries and public on disadvantages of pollution
brought together 24 countries in 1987 to sign the initial Montreal Protocol on Substances that Deplete the Ozone Layer
6.2.U7 An illegal market for ozone-depleting substances persists and requires consistent monitoring.
The black market in ozone-depleting substances (ODS) is a direct consequence of international agreement on targets to reduce and phase-out the production and consumption of such chemicals. The illegal trade in CFCs is undermining the ‘Montreal Protocol on Substances that Deplete the Ozone Layer’.
Reasons for the illegal trade:
ODS substitutes are often costlier than CFCs
Updating equipment to enable use of alternative chemicals is expensive
The lifetime of CFC containing equipment is long
Penalties in may countries are small.
As a result of the decline in the production and use of CFCs, and the continuation of CFC production in developing countries, the lure of illegal trade in CFCs is obvious. Significant volumes of illegal imports of CFCs into Western Europe have been reported, even though production in Western Europe ceased at the end of 1994. Unfortunately, the Montreal Protocol currently does not require countries to implement controls against illegal trade, although they have been urged to install verification programs to reduce illegal trade in ODCs.
6.2.U8 The Montreal Protocol on Substances that Deplete the Ozone Layer (1987) and subsequent updates is an international agreement for the reduction of use of ozone-depleting substances signed under the direction of UNEP. National governments complying with the agreement made national laws and regulations to decrease the consumption and production of halogenated organic gases such as chlorofluorocarbons (CFCs).
1997 Montreal Protocol
international agreement on the emission of ozone-depleting substances
froze production and consumption of CFC’s with goal of zero production by year 2000
LEDC’s granted a longer time to implement the treaty
China and India have not met their quotas under the MP because of their rapid economic growth and high demand for refrigeration & AC’s
good example of a successful international cooperative effort to alter human impact on the environment
Evaluate the use of ozone-depleting substances, and study the relative effectiveness of these agreements and the difficulties in implementing and enforcing them. Be familiar with what steps national governments are taking to comply with these agreements.
Applications and skills:
6.2.A1 Evaluate the role of national and international organizations in reducing the emissions of ozone-depleting substances.
UNEP (United Nations Environment Programme), forges international agreements, studies the effectiveness of these agreements, and the difficulties implementing and enforcing them.
The Montreal Protocol (1987), which is an international agreement on reduction of emission of ozone-depleting substances.
The signatories agreed to freeze production of many CFCs and halons and strongly reduce consumption and production of these substances by 2000.
Most countries followed the rules but China and India continued to produce and use huge amounts of CFCs.
But they have since both agreed to phase out the use of CFCs.
6.2 Stratospheric Ozone ppt
6.2 Stratospheric Ozone notes
Monitoring Tropospheric Ozone
The Ozone Layer Lab
Stratospheric Ozone activity
Montreal Protocol article
Ozone depletion vs Global Warming
Ozone Case Study
Ozone formation and destruction, as well as its link to global warming - Dynamic Science
Ozone - EPA
NASA’s Earth Observatory page on tropospheric ozone - NASA
Webster’s Online Dictionary entry for ozone
Tropospheric ozone processes. - Belgium Institute of Space Aeronomy
Health Effect of UV radiation - WHO
Positive and Negative Effects of UV Radiation - Science Learn
Convention on Long-Range Transboundary Air Pollution (LRTAP), Geneva, 1979 - Wikipedia
Vienna Convention for the Protection of the Ozone Layer, Vienna, 1985 - Wikipedia
Montreal Protocol on Substances that Deplete the Ozone Layer, Montreal 1987 - Wikipedia
In The News
Nations, Fighting Powerful Refrigerant That Warms Planet, Reach Landmark Deal - New York Times October 2016
Greenhouse gases deal will make little difference to west - Guardian Oct 2016
Ozone depletion: SA to phase out harmful gases but struggles to find suitable alternatives - Traveller24 Oct 2016
Ozone Hole Shows Signs of Shrinking, Scientists Say - New York Times Jun 2016
Ultraviolet Radiation: How It Affects Life on Earth - NASA · September 6, 2001
The depletion of ozone has global implications to ocean productivity and oxygen production.
National economic approaches may have an impact on international environmental discussions.
The Montreal Protocol was an international agreement created by the UN—can one group or organization decide what is best for the rest of the world?
CFCs and Ozone
NASA's been tracking the thinning of the ozone layer the south pole for nearly 20 years. In this slowed-down animation, you can watch the ozone hole's average size each October.
Excerpt from the TV documentary series "The Universe"
Restrictions on chemicals credited in ozone-hole shrinkage
The signing of the Montreal Protocol in September 1987 launched an unprecedented global effort in the protection of the environment. To this day, the Vienna Convention and the Montreal Protocol are the only universally ratified treaties, uniting 198 countries in taking on the fight against man-made ozone depleting substances.
Stratospheric Ozone (6.2)
Ozone -Oxygen Cycle - dynamic equilibrium
What are Ozone Depleting substances?
What is the Montreal Protocol?
Montreal Protocol- why it worked
ODS's on the black market